Solid Phase Extraction of Trace Copper(II) Using Modified Nano Polyacrylonitrile Fiber

Authors

1 Department of Chemistry, Varamin (Pishva) Branch , Islamic Azad University, Varamin, Iran

2 Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran

3 Department of Chemistry, Damghan Branch, Islamic Azad University, Damghan, Iran

Abstract

A simple method has been developed for the preconcentration of copper(II) based on the adsorption of its Modified nano polyacrylonitrile fiber. Modified nano polyacrylonitrile fiber (PANF) was prepared by adding of acrylic fibers to mSethanolamine (MMA) with different concentration solutions. The stability of a chemically Modified nano polyacrylonitrile fiber especially in concentrated hydrochloric acid which was then used as a recycling and pre-concentration reagent for further uses of modified nano polyacrylonitrile fiber. The application of this Modified nano polyacrylonitrile fiber for sorption of a series of metal ions was performed by using different controlling factors such as the pH of metal ion solution and the equilibration shaking time by the static technique. Cu (II) was found to exhibit the highest affinity towards extraction by these Modified nano polyacrylonitrile fiber phases. The pronounced selectivity was also confirmed from the determined distribution coefficient (Kd) of all the metal ions, showing the highest value reported for Cu (II) to occur by Modified nano polyacrylonitrile fiber. The potential applications ofModified nano polyacrylonitrile fiber for selective extraction of Cu(II) to occur from aqueous solution were successfully accomplished as well as pre- concentration of low concentration of Cu(II) (60 pg ml-1) from natural tap water with a pre-concentration factor of 100 for Cu(II) off-line analysis by flame atomic absorption analysis.

Keywords

References

  1. H.J.M.Bowen,Enviromental Chemistery of the
  2. Elements, Academic Press, New York,1979,
  3. pp.132-135.
  4. L.E.Brand, W.G. Sunda,R.R.L. Guillard,
  5. J.Exp.Mar.Biol.Ecol.96(1986)225.
  6. H.H. Taylor, J.M.Anstiss, Mar. Freshwat .
  7. Res.50(1999)907.
  8. F.M.M.Morel, R.J.M. Hudson,
  9. N.M.Price,Limnol.Oceanogr.36(1991)1742.
  10. A.S.Gordan,Mar.Chem.38(1992)1.
  11. J.W.Moffett, L.E.Brand, P.L. Croot,
  12. K.A.Barbeau,Limnol.Oceanoger. 42(1997)789.
  13. P.L.Croot,J.W.Moffett, L.E.Brand,
  14. Limnol.Oceanogr.45(2000)619.
  15. M.Wood,H.K.Wang,
  16. Environ.Sci.Technol.17(1983)582A.
  17. N.N.Greemwood, A.Eamshow,Chemistery of
  18. Elements, Pergamon Press, New York, 1984.
  19. C.A.Burtis, E.R.Ashwood,Tiets Textbook of
  20. Clinical Chemistery, third ed., Macmillan,New
  21. York,1999.
  22. B. Wetz, Atomic Absorption Spectroscopy,
  23. VCH, Amsterdam,1985.
  24. A.D.Eaton, L.S.Clesceri, A.E.Greenberg,
  25. Standard Methods for the examination of water
  26. and waste water ,19 th ed ,American Public
  27. Health Association, Washington,DC,1995.
  28. F.J.Welcher, E.Boschmann, Organic Reagents
  29. for Copper, Krieger Huntington, New
  30. York,1979.
  31. Z.Marczenko, Separation and
  32. Spectrophotometric Determination of
  33. Elements,Ellis Horwood, London, 1986.
  34. O.P.Bharagava, Talanta 16(1969)743.
  35. A.A. Schilt, W.C. Hoyle, Anal. Chem. 41(1964)
  37. L.G.Borchart, J.P. Butler, Anal. Chem.
  38. (1957) 414.
  39. R. Chaisuksant, W.P. Ayuthaya, K. Grudpan,
  40. Talanta 53 (2000)579.
  41. D. Kara, M. Alkan, Microchem. J. 71(2002) 29.
  42. K.Saito, S.Murakami, A. Muromatsu, E.Sekido,
  43. Anal.Chim. Acta 294(1994) 329.
  44. Phasecto
  45. K. Ikeda, S. Abe, Anl.Chim. Acta 363 (1998)
  47. S. Igarashi, N. Ide, Y.Takagai, Anal.Chim. Acta
  48. (2000) 263.
  49. J. Liu, W.Wang, G. Li, Talanta 53(2001)1149.
  50. A.N.Anthemidis, G.A. Zachariadis, J.A. Stratis,
  51. Talanta 54(2001)935.
  52. D. Zenedelovska, G. Pavlovska, K. Cundeva,
  53. T.Stafilov, Talanta 54(2001)139.
  54. M.Endo, K.Suziki, S.Abe, Anal. Chim. Acta
  55. (1998)13.
  56. K.Ohta, H.Tanahasi, T. Suzuki, S.Kaneco,
  57. Talanta 53(2001)715.
  58. V.Cuculic, M.Mlakar, M.Branica, Anal. Chim.
  59. Acta 339(1997)181.
  60. A.Moghimi, M.S.Tehrani, S.Waqif Husain,
  61. Material Science Research India 3(1a)
  62. (2006)27.
  63. .Zargaran M., Shoushtari A. M., Abdouss M., J.
  64. Appl. Polym. Sci. 2008, 110, 3843.
  65. Tabarzadi M., Abdouss M., Hasani S. A.,
  66. Shoushtary A.M., Mat.-wiss. u.Werkstofftech.
  67. , 41, No. 4,221
  68. .Shin D. H., Ko Y. G., Choi U. S., Kim W. N.,
  69. Ind. Eng. Res.2004, 43, 2060.
  70. M.S.Tehrani, A.Moghimi, S.Waqif Husain,
  71. Material Science Research India 3(2)
  72. (2005)135.
  73. E.M.Thurman,M.S.Mills,Solid-Phase
  74. Extraction, Principles and Practice, Wiley, New
  75. York, 1998.
  76. J.Pawliszyn, Solid-Phase Microextraction,
  77. Theory and Practice, Wiley-VCH, New York,
  79. R.M. Izatt, J.S. Bradshaw, R.L. Bruening, Pure
  80. Appl. Chem. 68(1996)1237.
  81. D.F.Hagen, C.G.Markell, G.A. Schmitt,
  82. Anal.Chim. Acta 236(1990)157.
  83. C.J.Krueger, J.A. Fild, Anal.Chem.
  84. (1995)3363.
  85. K.Z.Taylor, D.S.Waddell,E.J.Reiner,Anal.
  86. Chem. 67(1995)1186.
  87. Y.Yamini, M.Ashraf-Khorassani, J.High
  88. Resolut. Chromatogr.17(1994)634.
  89. M.Shamsipur, A.R.Ghiasvand, Y.Yamini,
  90. Anal.Chem. 71(1999)4892.
  91. M.Shamsipur, A.R.Ghiasvand, H. Sharghi, Int.
  92. J.Environ. Anal.Chem. 82(2001)23.
  93. Brunner, J.;Mokhir, A.;Kramer,
  94. R.J.Am.Chem.Soc. 125(2003)12410.
  95. Zelder, F.H.;Brunner, J.; Kramer, R. Chem.
  96. Commun.2004, 902.
  97. Boll, I.; Kramer, R.; Brunner, J.; Mokhir, A.
  98. J.Am.Chem. Soc. 27(2005)7849.
  99. MOGHIMI1, A. ; Oriental Journal of Chemistry
  100. ,22(3),527.
  101. Nayebi, P.; MOGHIMI, A.;Oriental Journal of
  102. Chemistry 2006,22(3),507.
  103. MOGHIMI, A.; "Chinese Journal of Chemistry
  104. ââ‚‌ 2007,25, 640.
  105. MOGHIMI, A.;"Chinese Journal of Chemistry ââ‚‌
  106. ,25,10, 1536.
  107. Moghimi, A.; Ghammamy S. "Environmental
  108. chemistry an Indian journal"2007,Vol.2,
  109. Issues 3.
  110. Choi,Y.S.;Choi,H.S.Bull.Korean Chem.
  111. Soc.24(2003)222.
  112. Saber Tehrani,M.; Rastegar,F.; Parchehbaf,
  113. A.;Rezvani,Z.;Chinese Journal of Chemistry
  114. (2005)1437.
  115. Takeshima, M.; Yokoyama, T. ; Imamoto, M.;
  116. Asaba, H. J. Org. Chem. 1969, 34,730
Journal of Chemical Health Risks

Volume 2, Issue 2
Spring 2012

Files

History

  • Receive Date: 31 July 2012
  • Revise Date: 05 December 2020
  • Accept Date: 29 October 2018

Share

How to cite

Statistics