Extraction and Determination of Trace Copper (II) Using Octadecyl Silica Membrane Disks Modified 1-(2-Pyridyl Azo) 2-Naphtol(Pan) in Water Samples and Paraffin-Embedded Tissues from Liver Loggerhead Turtles Specimens by FAAS

Authors

1 Department of Chemistry, Varamin (Pishva) Branch , Islamic Azad University, Varamin, Iran

2 2Department of Chemistry, Damghan Branch, Islamic Azad University, Damghan, Iran

Abstract

A simple and reproducible method for the rapid extraction and determination of trace amounts of copper(II) ions using octadecyl-bonded silica membrane disks modified by 1-(2-Pyridyl Azo)2-Naphtol(PAN)and Atomic Absorption Spectrometry was presented. The method was based on complex formation on the surface of the ENVI-18 DISKTM disks followed by stripping of the retained species by minimum amounts of appropriate organic solvents. The elution was efficient and quantitative. The effect of potential interfering ions, pH, ligand amount, stripping solvent, and sample flow rate were also investigated. Under the optimal experimental conditions, the break-through volume was found to about 1000mL providing a preconcentration factor of 500. In the present study, we reported the application of preconcentration techniques still continues increasingly for trace metal determinations by flame atomic absorption spectrometry (FAAS) for quantification of Cu in Formalin-fixed paraffin-embedded (FFPE) tissues from Liver loggerhead turtles. The maximum capacity of the disks was found to be 389± 4 µg for Cu2+.The limit of detection of the proposed method was 5ng per 1000mL.The method was applied to the extraction and recovery of copper in different water samples.

Keywords


H.J.M.Bowen.1979 .Enviromental Chemistery
of the Elements, Academic Press, New York,
-135 .
L.E.Brand, W.G. Sunda,R.R.L. Guillard.1986
J.Exp.Mar.Biol.Ecol.96:225.
H.H. Taylor, J.M.Anstiss.1999, Mar. Freshwat.
Res.50:907.
F.M.M.Morel, R.J.M. Hudson, N.M.Price,
Limnol.Oceanogr.36:1742.
A.S.Gordan, 1992 Mar.Chem.38:1.
J.W.Moffett, L.E.Brand, P.L. Croot,
K.A.Barbeau1997 ,Limnol.Oceanoger. 42:789.
P.L.Croot,J.W.Moffett, L.E.Brand,2000
Limnol.Oceanogr.45:619.
M.Wood, H.K.Wang, 1983
Environ.Sci.Technol.17:582A.
N.N.Greemwood, A.Eamshow, 1984
Chemistery of Elements, Pergamon Press, New
York.
C.A.Burtis, E.R.Ashwood,Tiets 1999 Textbook
of Clinical Chemistery, third ed.,
Macmillan,New York.
B. Wetz, 1985 Atomic Absorption
Spectroscopy, VCH, Amsterdam.
A.D.Eaton, L.S.Clesceri, A.E.Greenberg, 1995
Standard Methods for the examination of water
and waste water ,19 th ed ,American Public
Health Association, Washington,DC .
F.J.Welcher, E.Boschmann, 1979 Organic
Reagents for Copper, Krieger Huntington, New
York.
Z.Marczenko, 1986 Separation and
Spectrophotometric Determination of
Elements,Ellis Horwood, London.
O.P.Bharagava, 1969 Talanta 16:743.
A.A. Schilt, W.C. Hoyle, 1964Anal. Chem.
:344.
L.G.Borchart, J.P. Butler, 1957 Anal. Chem.
:414.
R. Chaisuksant, W.P. Ayuthaya, K. Grudpan,
Talanta 53:579.
D. Kara, M. Alkan, 2002 Microchem. J. 71: 29.
K.Saito, S.Murakami, A. Muromatsu,
E.Sekido, 1994 Anal.Chim. Acta 294:329.
K. Ikeda, S. Abe, 1998 Anl.Chim. Acta 363:
S. Igarashi, N. Ide, Y.Takagai, 2000
Anal.Chim. Acta 424:263.
J. Liu, W.Wang, G. Li, 2001Talanta 53:1149.
A.N.Anthemidis, G.A. Zachariadis, J.A. Stratis,
Talanta 54:935.
D. Zenedelovska, G. Pavlovska, K. Cundeva,
T.Stafilov, 2001 Talanta 54:139.
M.Endo, K.Suziki, S.Abe, 1998 Anal. Chim.
Acta 364:13.
M.E. Campderros, A. Acosta, J. Marchese,
Talanta 47:19.
I.Narin, M. Soylak, L.Elic, M.Dogan, 2000
Talanta 52:1041.
Y.Akama, M.Ito, S.Tanaka, 2000 Talanta
:645.
K.Ohta, H.Tanahasi, T. Suzuki, S.Kaneco,
, Talanta 53:715.
V.Cuculic, M.Mlakar, M.Branica, Anal. Chim.
Acta 339:(1997)181.
A.Moghimi, M.S.Tehrani, S.Waqif Husain,
Material Science Research India 3(1a)
:27.
M.S.Tehrani, A.Moghimi, S.Waqif Husain,
Material Science Research India 3(2)
:135.
E.M.Thurman,M.S.Mills, 1998 Solid-Phase
Extraction, Principles and Practice, Wiley, New
York.
J.Pawliszyn, 1997 Solid-Phase Microextraction,
Theory and Practice, Wiley-VCH, New York.,
R.M. Izatt, J.S. Bradshaw, R.L. Bruening, 1996
Pure Appl. Chem. 68:1237.
D.F.Hagen, C.G.Markell, G.A. Schmitt, 1990
Anal.Chim. Acta 236:157.
C.J.Krueger, J.A. Fild, 1995 Anal.Chem.
:3363.
K.Z.Taylor, D.S.Waddell,E.J.Reiner, 1995
Anal. Chem. 67:1186.
Y.Yamini, M.Ashraf-Khorassani, 1994 J.High
Resolut. Chromatogr.17:634.
M.Shamsipur, A.R.Ghiasvand, Y.Yamini, 1999
Anal.Chem. 71:4892.
M.Shamsipur, A.R.Ghiasvand, H. Sharghi,
Int. J.Environ. Anal.Chem. 82:23.
Brunner, J.;Mokhir, A.;Kramer, R. 2003
J.Am.Chem.Soc. 125:12410.
Zelder, F.H.;Brunner, J.; Kramer, R. 2004
Chem. Commun., 902.
Boll, I.; Kramer, R.; Brunner, J.; Mokhir, A.
J.Am.Chem. Soc. 27(2005)7849.
Hagen, D.F.;Mrkell, C.G.; Schmitt, G.A.;
Blevins, D.D.; Anal. Chim. Acta 236(1990)
.
Yamini, Y.; Alizadeh, N.; Shamsipur, M.; Anal.
Chim. Acta 69(1997) 355.
Petit de Pena, Y.; Gallego M.; Valcarcel, M.;
Anal. Chem. 67:2524 .
Alizadeh, N.; Naeimi, H.; Sharghi,H.;
Samsipur,Polish, M.; 1999 Polish
J.Chem.73:915.
Moghimi A, Poursharifi M.J. 2011, Australian
Journal of Basic and Applied Sciences, 5(6):
-986 ,
Choi,Y.S.;Choi,H.S. 2003 Bull.Korean Chem.
Soc.24:222.
Matoso,E.;Kubota,L.T.;Cadore,S. 2003
STalanta 60:1105.
Purachat, B.;
Liawruangrath,S.;Sooksamiti,P.;Rattanaphani,S
.;Buddhasukh, D.2001 Anal.Sci. 17:443.
Ensafi,A.A.;Abbasi,S.;Rahimi
Mansour,H.;Mohammad pour Baltork, I.
Anal.Sci. 17:609.
Saber Tehrani,M.; Rastegar,F.; Parchehbaf,
A.;Rezvani,Z,2005.Chinese Journal of
Chemistry 23:1437.
Moghimi A, R. Ghiasi, 2008 J. Korean Chem.
Soc., 52: 4.
Moghimi A., 2007; Chinese Journal of
Chemistry 12:1842-1847.
Hashemi, O. R.; Kargar-Razi, M.; Raoufi, F.;
Moghimi, A.; Aghabozorg, H.; Ganjali, M. R.
Microchem. J. 69: 1
Hashemi, O. R.; Raoufi, F.; Ganjali, M. R.;
Moghimi, A.; Kargar-Razi, M.; Aghabozorg,
H.; Shamsipur, M. 2000,Anal. Sci. 16: 1221.
Ganjali,M R ; Pourjavid, M. R.; Hajiagha
Babaei, L.;Niasari, M. S. 2004.Quim Nova 27:
Ganjali,M. R.; Pourjavid, M. R.; Hajiagha
Babaei, L.;Niasari, M. S. 2004.Ann. Chim.
(Rome) 94: 47.
Ganjali,M R.; Basiripour, F.; Niasari, M. S.
Can. 2002 J. Anal. Sci. Spect. 47: 41